SYNTHESES, REACTIONS, AND STRUCTURES OF CERTAIN SULFUR-NITROGEN COMPOUNDS.
Abstract
Sulfamide was shown to undergo condensation with monoketones to yield new carbon-nitrogen-sulfur heterocyclic compounds, to undergo condensation to various simple and methyl-substituted linear deammonation products some of which in turn formed trisubstituted phosphazo derivatives, and to form weak complexes of several types with various transition metal ions, notably Cu(2+). Alpha- and beta-Sulfanuric chloride trimers were synthesized, separated, and investigated by structure-indicating techniques. Alpha-Sulfanuric chloride was found to undergo ring cleavage with strong nucleophides, to yield isomeric substitution products with the more weakly basic morpholine, and to yield 'cis' and 'trans' fluorides. 'Cis' sulfanuric fluoride trimer has been converted to a number of isomeric phenylated and aminolyzed substitution products, all of which have been isolated and evaluated by infrared and nuclear magnetic resonance spectroscopy. The reactions of trichlorophosphazo-substituted phosphonitrilic chloride trimers with phenyl Grignard reagents have been explored and the products characterized similarly. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 31, 1969
- Accession Number
- AD0681940
Entities
People
- Therald Moeller
Organizations
- University of Illinois Urbana–Champaign