TIN-OXYGEN-PHOSPHORUS COMPOUNDS.
Abstract
Four types of tin-oxygen-phosphorus compounds are described and characterized. All of the compounds are oligomeric and incorporate either phosphinato or phosphonato bridging. Physical data are consistent with 5-coordinate tin for triorganotin diorganophosphinates, I; both 4- and 5-coordinate tin for bis (triorganotin) organophosphonates, II; 5-coordinate tin for poly (diorganotin organophosphonates), III; and 6-coordinate tin for diorganotin bis (diorganophosphinates), IV. Structures are proposed on the basis of molecularity, infrared, nmr, and Mossbauer data. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Mar 01, 1969
- Accession Number
- AD0684105
Entities
People
- D. L. Schmidt
- E. E. Flagg
- R. E. Ridenour