HYDROGEN BOND AND FREQUENCIES OF VALENCE OSCILLATIONS OF N - H- AND NO2-GROUPS OF NITROANILINES,

Abstract

Monoalkyl and aryl derivs. of o-NO2C6H4NH2 do not show any clear evidence of intramol H-bonding. This may be due to the positive charge present on the amino-N atom due to resonance and its effect on the vibration frequency of the H-atom that is not H-bonded. A table is given of the N-H and N O frequencies of 13 o-, m-, and p-nitroanilines. There are differences, slight in comparison with those of the nitrophenols which are better proton donors, which are attributed to intermol. H-bonding. (Author)

Document Details

Document Type
Technical Report
Publication Date
Nov 08, 1968
Accession Number
AD0686085

Entities

People

  • A. E. Lutskii
  • P. A. Chernyavskii

Organizations

  • National Air and Space Intelligence Center

Tags

DTIC Thesaurus Topics

  • Doppler Effect
  • Frequency
  • Frequency Shift
  • Hydrogen
  • Hydrogen Bonds
  • Motion
  • Nitrophenols
  • Oscillation
  • Resonance
  • Resonant Frequency
  • Vibration

Fields of Study

  • Chemistry

Readers

  • Atmospheric Science / Meteorology, specifically Wind Wave Turbulence.
  • Organic Chemistry
  • Quantum Chemistry