THE NMR SPECTRA OF NITRATE ESTERS
Abstract
The 1H spectra of twenty-one nitrate esters have been measured. These were the higher alkyl nitrates, from n-propyl to n-decyl nitrate, as well as iso-propyl and iso-butyl nitrates; ethylene, tri-, tetra-, and pentamethylene dinitrates; 2,2'-oxydiethyl dinitrate (diethylene glycol dinitrate); glycerol 1,3-dinitrate; 2-chlorotrimethylene dinitrate; meso-1,2-dimethylethylene dinitrate; and glycerol 1,2,3- and butane 1,2,4-triyl trinitrates. A complete analysis of the spectrum was not possible for any of the compounds: a number, like the corresponding fluorides, give deceptively simple spectra. In others the resolution is not sufficient to allow all the NMR parameters to be evaluated. A brief discussion of the parameters which were obtained, and their use in the analysis of mixtures is given.
Document Details
- Document Type
- Technical Report
- Publication Date
- Dec 19, 1968
- Accession Number
- AD0687225
Entities
People
- R. T. Fraser