APPLICATION OF THE LIQUID DISTRIBUTION METHOD TO THE STUDY OF THE HYDROLYSIS OF Ag(+)

Abstract

The distribution of silver at 25C between solutions of quinoline (Q) in benzene and 3 M Na(ClO4,OH) was studied as a function of (Q)org, (OH(-)) and the silver concentration. In these experiments the reaction Ag(+) (aq) + 2 Q (org) + ClO4(-) (aq) = AgQ2 ClO4 (org) (eq. const. log K = 3.23) was used for the study of the hydrolysis of Ag(+) in 3 M NaClO4 at low concentrations of silver. The data provide no evidence for the presence of significant amounts of polynuclear complexes. Furthermore, the data indicate that AgOH is not formed to any large extent in 3 M Na(ClO4,OH). In connection with the distribution experiments the distribution constant, K(d), of quinoline between various organic solvents and 3 M NaClO4 has been determined.

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Document Details

Document Type
Technical Report
Publication Date
Jul 30, 1959
Accession Number
AD0688503

Entities

People

  • David Dyrssen
  • P. J. Antikainen

Organizations

  • Royal Institute of Technology

Tags

DTIC Thesaurus Topics

  • Air Force
  • Chemical Synthesis
  • Chemistry
  • Chloroform
  • Equations
  • Hydrolysis
  • Inorganic Chemistry
  • Liquids
  • Measurement
  • Organic Solvents
  • Phase
  • Quinolines
  • Scientific Research
  • Silver Oxides
  • Solid Phases
  • Solubility
  • Solvents

Fields of Study

  • Chemistry

Readers

  • Materials Science and Engineering.
  • Organic Chemistry