AMMONIUM PERCHLORATE LINEAR PYROLYSIS BY CONVECTIVE SURFACE HEATING

Abstract

Ammonium perchlorate (AP) specimens were exposed to various levels of convective surface heating at one atmosphere ambient pressure. Surface regression rates were measured and, simultaneously, surface temperatures were determined by measuring the infrared emission near 3.1 microns. These data represent the first AP linear-pyrolysis characteristics obtained by means of convective surface heating. Previously, linear pyrolysis was obtained by pressing specimens against heated plates (solid and porous) and heated wire meshes. The subject data agree with some, and disagree with other, of these previous data. The usefulness of convective surface heating and radiometric techniques are evaluated. It is demonstrated that preliminary experiments are required to support their use in linear pyrolysis studies. According to the evaluation, previous radiometric work dealing with surface decomposition is open to substantial question. It is concluded that the subject techniques are viable and offer experimental compliments to other methods, but that none of the current techniques are without substantial shortcomings. Means of incorporation of AP linear pyrolysis results into theoretical models of the propellant deflagration process are discussed.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1969
Accession Number
AD0689383

Entities

People

  • Richard B. Cole
  • Robert F. Mcalevy Iii

Organizations

  • Stevens Institute of Technology

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Ammonium Perchlorate
  • Chemical Reaction Properties
  • Chemical Reactions
  • Combustion
  • Composite Materials
  • Composite Propellants
  • Deflagration
  • Lysis
  • Materials
  • Materials Laboratories
  • Measurement
  • Mechanical Engineering
  • Perchlorates
  • Propellants
  • Pyrolysis
  • Solid Propellants
  • Surface Temperature

Readers

  • Computational Modeling and Simulation
  • Rocket Propulsion.
  • Spectroscopy.