MECHANICS OF VISCOELASTIC COMPOSITES.

Abstract

An apparatus was developed to measure the dynamic mechanical properties of foamed materials filled with a viscous fluid, over a frequency range from 0.002 to 200 Hz. It has been tested using two model viscoelastic materials over the temperature range -50C to +100C. Measurements were then made on various foam/fluid systems including rubber latex, polyether and polyester foams filled with air, glycerin, silicone oil and water. The Gent-Rusch theory has been modified to take into account inertia effects, damping in the matrix material itself, and special features of the test-piece assembly. The modified theory is shown to describe the measurements successfully over the entire frequency range employed. Stress-optical coefficients have been determined for lightly-cross-linked samples of cis- and trans-polyisoprene, swollen to a high degree in a variety of non-polar solvents. A strong dependence on the geometrical asymmetry of the solvent molecule has been observed. Solvents with long straight molecules gave large values of the stress-optical coefficient whereas those with compact symmetrical molecules gave minimum values. This effect is attributed to short-range orientational order, due to packing effects in a molecularly-anisotropic medium. (Author)

Document Details

Document Type
Technical Report
Publication Date
May 01, 1969
Accession Number
AD0690612

Entities

People

  • Alan Neville Gent
  • N. C. Hilyard
  • S. V. Kanakkanatt

Organizations

  • University of Akron

Tags

DTIC Thesaurus Topics

  • Assembly
  • Asymmetry
  • Biomedical And Dental Materials
  • Coefficients
  • Composite Materials
  • Films
  • Frequency
  • Macromolecules
  • Materials
  • Measurement
  • Mechanical Properties
  • Mechanics
  • Molecules
  • Physics
  • Polyesters
  • Polyethers
  • Polymeric Films

Readers

  • Materials Science and Engineering.
  • Polymer Science and Engineering.
  • Quantum Chemistry