COMPLEXES OF B9H10CHP(-) AND B9H10CHAs(-) WITH GROUP VI METAL CARBONYLS.

Abstract

The photochemical reaction of (CH3)4N(B9H10CHE) (E = P or As) with group VI metal carbonyls lead to the formation of complexes of the general formula, (CH3)4N(B9H10CHEM(CO)5). Available evidence suggests that the phosphorus or arsenic atom of the ligand is sigma bonded to the metal carbonyl in these new derivatives. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1969
Accession Number
AD0691289

Entities

People

  • Don C. Beer
  • Howard T. Silverstein
  • Lee J. Todd

Organizations

  • Indiana University Bloomington

Tags

DTIC Thesaurus Topics

  • Carbonyl Complexes
  • Chemical Compounds
  • Chemical Reactions
  • Elements
  • Group 15 Elements
  • Phosphorus
  • Photochemical Reactions

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry