MASS THERMAL ANALYSIS OF HYDROXYLAMINE AND METHOXYAMINE PERCHLORATES
Abstract
Mass thermal analysis was used to study the thermal decomposition of hydroxylamine and methoxyamine perchlorates. The first step in the thermal decomposition of these salts is the proton transfer from the substituted ammonium ion to the perchlorate anion to form the free substituted amine and perchloric acid. Activation energies were determined to be 20.7 kcal/mole (65 to 77C) for the dissociation of hydroxylamine perchlorate, and 30 kcal/mole (53 to 77C) for the dissociation of methoxyamine perchlorate.
Document Details
- Document Type
- Technical Report
- Publication Date
- May 01, 1969
- Accession Number
- AD0692492
Entities
People
- Berge B. Goshgarian
Organizations
- Air Force Research Laboratory