Investigation of Phosphorus-Containing Compounds Based on Diakyl Hydroquinone Derivatives as Additives for Lubricating Oils

Abstract

Some phosphites prepared from 2,5-di-tert-butylhydroquinone (I) and 2,5-di-tert-amylhydroquione (II) contg. 6.2-8 percent P, were investigated as additives for a diesel oil. The stability of the oil with 0.1 percent of these additives, detd. as time necessary for absorbing 10 ml. 0 at 175F, increased from 255 to 340-388 min. The corrosiveness of the oil with 1 percent additives decreased from 360 to 57-0.9 g./sq. m in the presence of 0.02 percent Cu naphthenate at 140 degrees for 25 hrs. Also, the gum-formation coeff. decreased simultaneously. The most efficient were the additives prepd. by condensation of phenyl-, and p-tert-amylphenylphosphorous acids with I and II, regarding both stability and anticorrosive properties. The formulas of the additives and their effects on the corrosiveness and stability of the oil are tabulated. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Jun 11, 1969
Accession Number
AD0693516

Entities

People

  • A. A. Vagabova
  • I. M. Orudzheva

Organizations

  • National Air and Space Intelligence Center

Tags

DTIC Thesaurus Topics

  • Additives (Chemicals)
  • Condensation
  • Dermatologic Agents
  • Lubricating Oils
  • Phosphorus
  • Plastic Explosives
  • Specialty Uses Of Chemicals

Readers

  • Analytical Chemistry
  • Mathematics or Statistics
  • Petroleum Engineering