GAS CHROMATOGRAPHIC DETERMINATION OF ETHYLENE GLYCOL IN USED OILS.

Abstract

Reduced performance and sometimes complete failure of internal combustion engines can be, at times, attributed to contamination of crankcase oil by the presence of glycol antifreeze. In the course of testing used crankcase oils, it is advantageous to be able to detect the presence of glycol and determine its concentration. This report describes a rapid new analytical procedure for the determination of ethylene glycol in crankcase oil using programmed temperature gas chromatography. The procedure involves the conversion of ethylene glycol to its trimethylsilyl derivative prior to chromatographing; identification and determination is obtained from the time incident and magnitude of the ethylene glycol peak appearing on the chromatogram. (Author)

Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1969
Accession Number
AD0694360

Entities

People

  • George G. Esposito
  • Robert G. Jamison

Tags

DTIC Thesaurus Topics

  • Alkenes
  • Chromatography
  • Combustion
  • Crankcases
  • Engines
  • Ethylene Glycol
  • Ethylenes
  • Gas Chromatography
  • Glycols
  • Internal Combustion Engines

Readers

  • Analytical Chemistry
  • Electrical Engineering
  • Organic Chemistry