TRANSANNULAR INTERACTIONS OF HETERO ATOMS IN MEDIUM-SIZED HETEROCYCLIC COMPOUNDS.
Abstract
An examination was made of the role which heterocyclic atoms, strategically located in medium-sized rings, play in reactions which are known from related carbocyclic systems to proceed with a high degree of carbonium ion character. Research centered on the following topics: Acid-promoted rearrangements involving transannular ether oxygen participation; brosylate acetolysis; and photoisomerization of selected 3-cycloheptenone derivatives. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Sep 15, 1969
- Accession Number
- AD0695705
Entities
People
- Leo A. Paquette
Organizations
- Ohio State University