CHEMISTRY OF STRAINED OLEFINS.

Abstract

Final report on studies concerned with the experimental tests of theory in bond breaking reactions of strained ring compounds. The first test of orbital symmetry control of a thermal 1,3-sigmatropic rearrangement was established. Preliminary work was carried out on the construction of a test in the 1,5-sigmatropic case. New synthetic approaches have been developed to the optically active cycloheptatrienes needed for stereochemical experiments. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1969
Accession Number
AD0697089

Entities

People

  • Jerome A. Berson

Organizations

  • University of Wisconsin–Madison

Tags

DTIC Thesaurus Topics

  • Acyclic Hydrocarbons
  • Alkenes
  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Construction
  • Cyclic Compounds
  • Cycloheptatrienes
  • Organic Chemistry
  • Symmetry

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Software Engineering

Technology Areas

  • Space