SENSITIVITY FUNDAMENTALS.

Abstract

The effect of confinement on the initiation of low-velocity detonation (LVD) was studied with particular emphasis on the confinement strength and charge length. Using 1,2-bis(difluoramino)-2-methylpropane (IBA) as a model compound, it was found that there was a slight increase in the apparent LVD gap sensitivity when the ratio of charge length L to the charge diameter D was increased threefold. Studies with both IBA and ethyl nitrate indicate that for these compounds the use of a witness plate as an LVD detector causes only a slight increase in the apparent LVD gap sensitivity. Work was also concentrated on refining previous shock temperature calculations on unreacted carbon tetrachloride and nitromethane. In particular, a more satisfactory form of the Hugoniot, was incorporated. The decomposition of vibrationally excited CH3NF2 was studied, and through appropriate RRKM analysis the rate parameters for CH3NF2 yielding 2HF + HCN were determined. (Author)

Document Details

Document Type
Technical Report
Publication Date
Nov 15, 1969
Accession Number
AD0698500

Entities

People

  • D. S. Ross
  • D. Tegg
  • J. Richard Shaw
  • M. E. Hill
  • R. W. Wollfolk

Organizations

  • SRI International

Tags

DTIC Thesaurus Topics

  • Carbon Tetrachloride
  • Chemical Compounds
  • Decomposition
  • Detectors
  • Detonations
  • Diameters
  • Hydrocarbons
  • Nitromethane
  • Organic Compounds
  • Physical Properties
  • Refining
  • Sensitivity
  • Warning Systems

Readers

  • Combustion Dynamics and Shock Wave Physics.
  • Organic Chemistry