INTERFACIALLY ACTIVE METALS IN METAL-CERAMIC COMPOSITES

Abstract

The role of the interface in metal-oxide composite materials has been investigated to determine the nature of bonding where an interfacially active metal has been used to promote wetting. A model system of Ag-MgO was used with titanium as the wetting agent. Electron diffraction was used to identify the magnesium titanate structure at the surface of the MgO crystal and the titanium oxides found in the adjacent titanium layer. Infiltration of the titanium oxide-magnesium titanate interface with liquid silver results in a separation of the solid oxide surfaces and the wetting and spreading of silver on the titanate surface. It is shown that the change in structure of the MgO surface must be taken into account when assessing the wetting phenomenon whenever an interfacially active metal is employed.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1969
Accession Number
AD0700121

Entities

People

  • Albert P. Levitt
  • Marc H. Richman
  • Robert D. French

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Ceramic Matrix Composites
  • Composite Materials
  • Diffraction
  • Electron Diffraction
  • Electrons
  • Free Energy
  • Magnesium
  • Materials
  • Materials Science
  • Metal Oxides
  • Metals
  • Oxides
  • Surface Energy
  • Surface Properties
  • Titanates
  • Titanium
  • Titanium Oxides

Fields of Study

  • Materials science

Readers

  • Reinforced Composite Materials
  • Superconducting Magnet Technology
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene