SIMPLE AND ACCURATE APPROXIMATION FOR THE CENTRIFUGAL FACTOR IN RRKM THEORY.
Abstract
An approximate form for the low pressure centrifugal effect is derived for Rice-Ramsperger-Kassel-Marcus (RRKM) unimolecular rate theory calculations. Comparisons are made with earlier approximations and with a more exact result. The effects on the observed activation energy and extension to the region of fall-off are described. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 15, 1970
- Accession Number
- AD0700207
Entities
People
- Benton Seymour Rabinovitch
- E. V. Waage
Organizations
- University of Washington