INTERACTION OF BORON TRIHALIDES WITH HEXAFLUOROACETONE IMINE,

Abstract

Boron trifuluoride forms a 1:1 addition compound with (CF3)2CNH. In contrast, BCl3 and BBr3 add across the CN double bond of the imine to yield (CF3)2CX-NH-BX2 derivatives. The structure of these aminoboranes was verified by vibrational spectroscopy. (Author)

Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1969
Accession Number
AD0701701

Entities

People

  • Clifford D. Miller
  • Kenneth E. Blick
  • Kurt Niedenzu

Organizations

  • University of Kentucky

Tags

DTIC Thesaurus Topics

  • Contrast
  • Mental Processes
  • Perception
  • Spectroscopy

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry