SALTING EFFECTS IN SEVERAL ALCOHOL-ELECTROLYTE-WATER SYSTEMS,

Abstract

Salting effects of sodium sulfate, potassium fluoride, potassium chloride, sodium perchlorate, and perchloric acid on cyclohexanol, 1-pentanol, and 1-butanol were determined by measuring the solubilities of the alcohols in the various electrolyte solutions. Solubilities were determined by color development and spectrophotometry. The relevant Setschenow parameters are reported. There was no apparent correlation between the salting effect and the dipole moment of the alcohol. These data can be used to interpret results of studies of the adsorption of the alcohols at electrode surfaces in the presence of these salts. (Author)

Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1969
Accession Number
AD0701702

Entities

People

  • Abdul K. Shallal
  • Harold R. Campbell
  • Henry H. Bauer

Organizations

  • University of Kentucky

Tags

DTIC Thesaurus Topics

  • Acids
  • Adsorption
  • Alcohols
  • Chemical Compounds
  • Chlorides
  • Chlorine Compounds
  • Cyclohexanols
  • Dipole Moments
  • Electrodes
  • Electrolytes
  • Fluorides
  • Halides
  • Halogen Compounds
  • Perchloric Acid
  • Potassium
  • Potassium Chloride
  • Solubility

Readers

  • Analytical Chemistry
  • Materials Science and Engineering.