RAMAN SCATTERING FROM THE HYDROXYL ION IN ALKALI HALIDES.
Abstract
Raman scattering has been observed from the hydroxyl ion in NaCl, Kcl, and KBr crystals. The measurements were made using an argon ion laser as a light source and a tandem double monochromator with photoelectric detection. A Raman emission attributed to the stretching motion of the OH9(-) ion was seen in all samples. The stretching bands in KBr:OH(-) and KCl:OH(-) showed no resolvable structure. However, at 15 K, the stretching band in NaCl:OH(-) appeared to be composed of two lines separated by about 2.8/cm. RRaman scattering from the stretching level of OD(-) doped NaCl was observed whereas no corresponding infrared absorption has been seen. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jul 01, 1969
- Accession Number
- AD0705535
Entities
People
- Wayne Robert Fenner
Organizations
- University of Illinois Urbana–Champaign