THE CHLORINATION OF C2B5H7.

Abstract

The closo-carborane, C2B5H7, reacts rapidly with Cl2 in the presence of AlCl3 to form HCl and 4-ClC2B5H6. The reaction without AlCl3 is accelerated by light forming, in addition to the 4-isomer, 1-ClC2B5H6 and 2-ClC2B5H6. The identity and structure of the new compounds are indicated by their mass spectra and 11B nmr spectra. A trans effect is observed in the 11B nmr of the 1-chloro derivative and reciprocal effects are observed in all compounds. (Author)

Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1970
Accession Number
AD0705613

Entities

People

  • Don Paquin
  • Gary Dunks
  • John R. Spielman
  • Richard Warren
  • Thomas Onak

Organizations

  • California State University, Los Angeles

Tags

DTIC Thesaurus Topics

  • Chlorination
  • Diffraction
  • Identities
  • Mass Spectra
  • Particle Spectra
  • Spectra
  • Wave Phenomena

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Organic Chemistry
  • Quantum Chemistry