MONOCARBON CARBORANES. IV. POLYHEDRAL ARSA- AND STIBACARBADODECABORANE (11) DERIVATIVES AND RELATED 11-ATOM CAGE FRAGMENTS.
Abstract
The syntheses of 1,2-, 1,7-, and 1,12-B10H10CHAs as well as 1,2-, and 1,7-B10H10CHSb are discussed. The conversions of the appropriate icosahedral derivative to 7,8-, or 7,9-B9H10CHAs-, 7,9-B9H10CHAsCH3 or 7,8-B9H10CHSb- are described. The synthesis and X-ray diffraction study of (C5H5)Co(1,2-B9H9CHAs) confirm the relative position of the carbon and arsenic atoms in the 1,2-arsa-carboranes and show the distorted nature of these derivatives. Dipole moment and nmr data are presented which aid in elucidating the role of the group V atom in these molecules. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- May 01, 1970
- Accession Number
- AD0706771
Entities
People
- Aaron R. Burke
- Albert R. Garber
- Bruce N. Storhoff
- Howard T. Silverstein
- Lee J. Todd
Organizations
- Indiana University Bloomington