A SPECTROSCOPIC STUDY OF FERROCENE AND RELATED COMPOUNDS.

Abstract

The work discussed in the report is involved with an attempt to explain discrepancies between an earlier vibrational assignment and recent studies of ferrocene, and its derivatives. Low temperature infrared and Raman work has been carried out showing some new and interesting features. The Raman study of a single crystal of ferrocene showed useful polarization features and is used to compare and contrast the original assignment with its alternatives. The infrared spectrum of the solid shows definite evidence for a breakdown in the selection rules. Factor group splitting is of the order of 2/cm. Force field calculations and the preparation and spectra of any related compounds considered to be appropriate are also discussed herein. (Author)

Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1970
Accession Number
AD0706925

Entities

People

  • Ivan J. Hyams

Organizations

  • Bowdoin College

Tags

DTIC Thesaurus Topics

  • Contrast
  • Crystals
  • Diffraction
  • Electromagnetic Spectra
  • Ferrocenes
  • Infrared Spectra
  • Low Temperature
  • Polarization
  • Single Crystals
  • Spectra
  • Splitting
  • Wave Phenomena

Readers

  • Organizational Psychology.
  • Polymer Science and Technology
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.