THE PYROLYSIS OF TETRAFLUOROHYDRAZINE.

Abstract

The pyrolysis of tetrafluorohydrazine was studied in a passivated monel bulb over the temperature range 315-520C and at pressures from about 30-700 torr. The stoichiometry was confirmed by gas chromatographic analysis, and the reaction kinetics investigated manometrically and analytically. 6NF2 yields 4NF3 + N2. The reaction rate was found to exhibit good second order behavior at temperatures above 405C. Evidence is presented that the reaction is homogeneous and the mechanism is bimolecular. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1970
Accession Number
AD0707784

Entities

People

  • Joseph B. Levy
  • Warren N. Corbin

Organizations

  • George Washington University

Tags

DTIC Thesaurus Topics

  • Analytical Chemistry Techniques
  • Chemical Analysis
  • Chemical Kinetics
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemistry
  • Chromatographic Analysis
  • Dynamics
  • Kinetics
  • Liquid Rocket Oxidizers
  • Physics
  • Pyrolysis
  • Stoichiometry

Fields of Study

  • Chemistry

Readers

  • Combustion science or combustion engineering.
  • Organic Chemistry