INTERFACE EFFECTS IN MASS TRANSFER CONTROLLED CORROSION REACTIONS

Abstract

The purpose of the investigation was to delineate the role played by surface active agents in mass transfer-controlled corrosion reactions in a saline environment. Major effort was directed toward dynamic systems where the metal surface moves relative to the saline solution. The galvanostatic polarization technique has been used to detect the specific role of concentration and chain length of amine surfactants in the corrosion reaction at the metal-aqueous solution interface, specifically at the Monel-saline solution interface. The chain length effect, i.e. increased corrosion inhibition with increased chain length, is considered to be related to hemi-micelle formation or two-dimensional condensation of adsorbed surfactant.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1970
Accession Number
AD0709468

Entities

People

  • D. W. Fuerstenau
  • I. Cornet

Organizations

  • University of California, Berkeley

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Aqueous Solutions
  • Cathodic Protection
  • Chemistry
  • Corrosion
  • Corrosion Inhibition
  • Current Density
  • Diffusion Coefficient
  • Engineering
  • Inhibition
  • Inhibitors
  • Mass Transfer
  • Materials
  • Materials Science
  • Metals
  • Saline Solution
  • Two Dimensional
  • Water

Readers

  • Analytical Chemistry
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Systems Analysis and Design