SYNTHESIS AND REACTIONS OF NOVEL BRIDGED DICARBOLLIDE COMPLEXES HAVING ELECTRON DEFICIENT CARBON ATOMS.
Abstract
Reaction of the bis-pi-dicarbollide ligand complexes of Co(+3) and Fe(+3) with CS2 in the presence of AlCl3 and HCl produced the firts examples of zwitterionic species having an -S-CH(+)-S- bridge between boron atoms of the two dicarbollide ion ligands of the complex. Similarly, a suspected -OC(CH3)(+)O- bridged species results from the reaction of acetic acid/acetic anhydride with an HClO4 catalyst. Further transformations of these species are described. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Aug 03, 1970
- Accession Number
- AD0710757
Entities
People
- James N. Francis
- M. Frederick Hawthorne
Organizations
- University of California, Riverside