IRON (II)-AND MANGANESE(I)-CARBORANE COMPLEXES FORMED THROUGH METAL-CARBON sigma-BONDS.
Abstract
Reaction of 1-lithiocarboranes with manganese pentacarbonyl bromide and cyclopentadienyl iron dicarbonyl iodide gives rise to a series of stable neutral derivatives containing a metal-carbon sigma-bond. Reaction of 1,10-dilithio-1,10-dicarba-closo-decaborane(10), formed from 1,10-dicarba-closo-decaborane(10) and two mole equivalents of n-butyllithium in ethereal solvents, with 2 mole equivalents of cyclopentadienyl iron dicarbonyl iodide, gives rise to an analogous derivative containing two non-chelating metal-carbon sigma bonds. The preparation, characterization, reactions, and proposed structures of these complexes are discussed. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Aug 10, 1970
- Accession Number
- AD0710759
Entities
People
- David A. Owen
- James C. Smart
- M. Frederick Hawthorne
- Philip M. Garrett
Organizations
- University of California, Los Angeles