THE CHEMISTRY OF BIS(pi-(3)-1,2-DICARBOLLYL) METALATES. PROTONATION AND B-SUBSTITUTION.

Abstract

The 'sandwich' bonded (bis(pi-(3)-1,3-dicarbollyl)Fe(II))(-2) ion is protonated in strongly acidic media to form what may prove to be the analog of protonated ferrocene. This species readily reacts with dialkyl-sulfides to form B-substituted bis(dicarbollyl)iron(II) and -(III) species. Analogous reactions have been carried out employing bis(dicarbollyl)iron (III) and -cobalt(III) anions. The preparation, characterization and structures of these complexes are discussed. (Author)

Document Details

Document Type
Technical Report
Publication Date
Sep 14, 1970
Accession Number
AD0712498

Entities

People

  • Kenneth P. Callahan
  • Leslie F. Warren Jr.
  • M. Frederick Hawthorne
  • Neill F. Travers

Organizations

  • University of California, Los Angeles

Tags

DTIC Thesaurus Topics

  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Ferrocenes
  • Inorganic Chemistry
  • Iron Organic Compounds
  • Organic Chemistry

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry