STUDIES IN STEREOCHEMISTRY.

Abstract

Brief summaries are presented on stereochemical research on the following topics: Synthesis and configuration of phosphine oxides; Hexachlorodisilane: A novel reducing agent for organic oxides and sulfides; Optical purity of phosphines by NMR; Pseudorotation and the stereochemistry of displacement reactions; Stereomutation of phosphine oxides by lithium aluminum hydride; Optical rotatory power; (2,3)-Sigmatropic rearrangements; and Energy barriers in pyramidal inversion process.

Document Details

Document Type
Technical Report
Publication Date
Sep 24, 1970
Accession Number
AD0712718

Entities

People

  • Kurt Mislow

Organizations

  • Princeton University

Tags

Communities of Interest

  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Aluminum
  • Aluminum Hydride
  • Chemical Compounds
  • Chemistry
  • Displacement
  • Displacement Reactions
  • Hydrides
  • Hydrogen Compounds
  • Inversion
  • Oxides
  • Phosphine
  • Phosphine Oxides
  • Reducing Agents
  • Stereochemistry

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Quantum Chemistry