Low-Temperature Phases of Interfacial Water in Clay-Water Systems

Abstract

Low temperature differential thermal analyses of selected clay-water systems were made to locate important phase change temperatures and to define fruitful temperature-pressure fields for precise calorimetric investigation. In addition to an exotherm corresponding to initial freezing, one, two or three exotherms were observed between -35C and -60C. The low temperature exotherms do not depend critically upon water content, but clearly they are related to clay mineral and exchangeable cation type. The evolution of heat in this temperature range probably corresponds to a phase change in the interfacial water.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1970
Accession Number
AD0715714

Entities

People

  • Allen R. Tice
  • Duwayne M. Anderson

Organizations

  • Cold Regions Research and Engineering Laboratory

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemistry
  • Cold Regions
  • Differential Thermal Analysis
  • Engineering
  • Heat Capacity
  • Heat Energy
  • Heat Of Fusion
  • Latent Heat
  • Low Temperature
  • Magnetic Resonance
  • Measurement
  • Nuclear Magnetic Resonance
  • Phase Transformations
  • Phyllosilicates
  • Soil Science
  • Thermal Analysis
  • Transition Temperature

Readers

  • Agricultural Chemistry/Soil Science
  • Computational Linguistics
  • Polymer Science and Technology