Metal Oxide Chemistry and Infrared Band Intensities.

Abstract

Shock tube experiments to measure the Fe + O2 gas phase reaction rate and the FeO fundamental band intensity, by using iron penetacarbonyl as a source of iron atoms, are described. A lower bound for the reaction Fe + O2 kl to FEO + O of K(1) = 3 X 10 to the 12th cu cm/(mole sec) for T > or + 2400K and an integrated fundamental FeO band intensity of 450/ama sq cm are reported. In addition the rate of vibrational relaxation of CO by Fe-atoms for T = 1400-1900K is given. Calculations for similar experiments on Al + O2 by the use of trimethylaluminum as a source of aluminum atoms are presented. (Author)

Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1970
Accession Number
AD0716493

Entities

People

  • C. W. Von Rosenberg Jr.
  • Kurt L. Wray

Tags

DTIC Thesaurus Topics

  • Aluminum
  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Intensity
  • Metal Oxides
  • Metals
  • Oxides
  • Physical Chemistry
  • Physics
  • Shock Tubes
  • Trimethylaluminum
  • Tubes
  • Vibrational Relaxation

Readers

  • Combustion science or combustion engineering.
  • Materials Science and Engineering.