The Catalytic Decomposition of the Fire Extinguishant Bromotrifluoromethand, CBrF3.

Abstract

A study was made of the catalytic decomposition of bromotrifluoromethane, CBrF3, in air using a bench-scale reactor which simulates the CO/H2 catalytic burner of nuclear submarines. There was no indication of thermal decomposition of CBrF3 in presence of stainless steel at temperatures up 700F. In contact with Hopcalite catalyst under conditions of the shipboard CO/H2 burner, there was no detectable decomposition of CBrF3 at 600F and 100 ppm influent concentration. The extent of decomposition of CBrF3 appeared to be 3% or less under the most severe conditions studied. The presence of CBrF3 in the air did not interfere with the oxidation of carbon monoxide by the catalytic burner. (Author)

Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1970
Accession Number
AD0716737

Entities

People

  • James K. Musick

Organizations

  • United States Naval Research Laboratory

Tags

DTIC Thesaurus Topics

  • Carbon Monoxide
  • Catalysts
  • Chemical Compounds
  • Decomposition
  • Dielectric Gases
  • Monoxides
  • Nuclear Powered Submarines
  • Oxidation
  • Shipboard
  • Stainless Steel
  • Steel
  • Submarines

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Fire Suppression Systems Design.
  • Tribology (the study of the boundary interaction between sliding surfaces, lubrication, wear and friction).