Stability of the Molecular Sieve Structure in Hostile Environments

Abstract

Proposals for the use of molecular sieves as regenerable CO2 and/or H2O absorbers in closed spaces have usually been based on their demonstrated efficiencies in pure atmospheres. The previously unknown effect of thermal cycling in more hostile environments containing a nominally stable halogenated hydrocarbon has been investigated. While the test halocarbon (dichlorodifluoromethane) was not itself deleterious, the acid products resulting from the molecular sieve-promoted decomposition of the compound caused structural damage to the sieves, which severely affected their capacities for CO2 and H2O. Sieves of the 5A and 10A type were investigated under a variety of conditions, with the 5A sieve being the more resistant to damage.

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Document Details

Document Type
Technical Report
Publication Date
Dec 07, 1970
Accession Number
AD0716748

Entities

People

  • D. D. Williams
  • E. T. Johnson
  • Roman R. Miller

Organizations

  • United States Naval Research Laboratory

Tags

Communities of Interest

  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Absorption
  • Barometric Pressure
  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Decomposition
  • Halogenated Hydrocarbons
  • Heat Transfer
  • Inorganic Chemistry
  • Materials
  • Measurement
  • Molecular Sieves
  • Nuclear Powered Submarines
  • Partial Pressure
  • Submarines
  • Thermal Conductivity
  • Vapor Pressure

Readers

  • Combustion science or combustion engineering.
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Fire Suppression Systems Design.

Technology Areas

  • Space