Disproportionation-Recombination Ratios of Large Branched Alkyl Radicals.

Abstract

The study of the disproportionation of alkyl radicals has been extended to large branched pentyl-2 radicals. Contrary to the belief based on small radical behavior, steric and activation energy effects are shown to be important. Existing data in the literature are summarized from the point of view of entropy effects. (Author)

Document Details

Document Type
Technical Report
Publication Date
Dec 30, 1970
Accession Number
AD0716789

Entities

People

  • Benton Seymour Rabinovitch
  • C. W. L:arson
  • J. H. Georgakakos

Organizations

  • University of Washington

Tags

DTIC Thesaurus Topics

  • Chemical Reaction Properties
  • Disproportionation
  • Energy
  • Heat Of Activation
  • Literature

Readers

  • Combustion science or combustion engineering.
  • Organic Chemistry