Final Results of On-Line Mass Spectrometric Analysis of Nonequilibrium Airflows

Abstract

Comprehensive determinations of nonequilibrium airflow compositions were made in frozen expansions of arc-heated air in a low-density wind tunnel nozzle. Reservoir conditions included pressures of from 3.7 to 20.8 atm and temperatures of from 2120 to 5380K. The experimentally determined compositions were correlated with the reservoir entropy. At low entropy, the concentrations of molecular species were generally in close agreement with predictions based on finite rate expansion calculations, but at high entropy, where nonequilibrium effects are large, considerable deviations from the predictions were observed. The molecular oxygen content was determined to be 7 percent greater than expected. The atomic oxygen concentration was determined to be consistently less than the theoretical prediction for all values of entropy, by as much as 9 percent of the total sample in the worst case.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1971
Accession Number
AD0718955

Entities

People

  • R. E. Dix
  • W. N. Macdermott

Organizations

  • Arnold Engineering Development Complex

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Accuracy
  • Air Force
  • Boundary Layer
  • Chemical Reactions
  • Liquid Hydrogen
  • Low Density
  • Mass Spectra
  • Mass Spectrometers
  • Measurement
  • Pressure Measurement
  • Resistance
  • Spectra
  • Spectrometers
  • Vacuum
  • Vacuum Chambers
  • Wind Tunnel Tests
  • Wind Tunnels

Fields of Study

  • Physics

Readers

  • Fluid Dynamics.
  • Materials Science and Engineering.
  • Molecular Photonics/Laser Physics