Acid-Base Equilibria and Titrations and Electrochemical Equilibria in Acetonitrile.

Abstract

Very briefly discussed are studies which have been made of acid-base equilibria and titrations and also of conjugation in acetonitrile (AN) as a solvent. Dissociation constants of a host of uncharged and cationic acids have been determined, including acid-base indicators. The protonation constants of water, methanol, butanol and diethylether in AN have been determined. The heteroconjugation constants of sulfate and bisulfate ions in AN with uncharged hydrogen bond donors have been determined. (Author)

Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1971
Accession Number
AD0721177

Entities

People

  • I. M. Koltoff

Organizations

  • University of Minnesota

Tags

DTIC Thesaurus Topics

  • Acetonitrile
  • Acid-Base Indicators
  • Acids
  • Alcohols
  • Chemical Compounds
  • Dissociation
  • Hydrogen
  • Hydrogen Bonds
  • Indicators
  • Methanols
  • Nitriles
  • Organic Compounds
  • Titration

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Organic Chemistry