Structure of the Double Layer at Solid Solution Interfaces.

Abstract

The structure of the electric double layer as solid metal solution interfaces has been studied. A new technique, based on electrocapillary thermodynamics, has been developed to determine surface excess charge at a given electrode for various electrode potentials and solution concentrations. The technique makes use of rapid immersion of dry electrodes into solution and following the current required to establish the interfacial region. With this technique, surface excess Cl(-) ions has been determined at gold electrodes. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1971
Accession Number
AD0721718

Entities

People

  • Alexander Damjanovic
  • John O'm. Bockris
  • Yoshiharu Matsuda

Organizations

  • University of Pennsylvania

Tags

DTIC Thesaurus Topics

  • Dielectric Properties
  • Electric Double Layer
  • Electrical Equipment
  • Electrical Properties
  • Electricity
  • Electrodes
  • Solid Solutions
  • Thermodynamics

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies