Complex Metal Hydrides. High Energy Fuel Components for Solid Propellant Rocket Motors.

Abstract

The report is comprised of the following papers of which the last six are reprints: Concerning the preparation of HMgAlH4 and HMgBH4; Concerning the reactions of lithium and sodium aluminum hydride with grignard reagents in diethyl-ether; Complex metal hydrides of magnesium--preparation and characterization of MMgRnH(3-n)compounds; Concerning the preparation of alkylmagnesium hydrides; Synthesis of N-trialkylborzines from phenyl borate, aluminum and hydrogen and primary amines; Reaction of lithium aluminum hydride with secondary amines in diethyl ether; Preparation of new complex metal hydrides--K2ZnH4 and Na2ZnH4; A convenient and economic route to reactive magnesium hydride; The Direct Synthesis of aminoalanes; The composition of complex metal hydrides in polar solvents-tertiary amines; Concerning the reaction of lithium aluminum hydride with diethylmagnesium in diethyl ether; Reaction of aluminum hydride with diethylmagnesium in tetrahydrofuran; and the Preparation of potassium trihydridomagnesiate, KMgH3.

Document Details

Document Type
Technical Report
Publication Date
Apr 16, 1971
Accession Number
AD0722374

Entities

People

  • E. C. Ashby

Organizations

  • Georgia Tech

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Aluminum
  • Aluminum Hydride
  • Grignard Reagents
  • High Energy
  • Hydrides
  • Hydrogen
  • Magnesium
  • Metals
  • Propellants
  • Rocket Engines
  • Solid Propellants

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Rocket Propulsion.