Effect of Eutectic Microstructure on the Properties of Ceramic Oxides.

Abstract

Continued development of equipment and techniques to produce well-controlled, directionally solidified oxide eutectic ingots was undertaken. With eutectics exhibiting melting temperatures below approximately 1550C, bottom cooling of contained melts generally resulted in poorly controlled eutectic micro-structures due to the low liquid-solid thermal gradients caused by the thermal insulation of the growing ingot. Various floating-zone, directional solidification approaches were successfully developed which used resistance heaters surrounding and/or in direct contact with the molten ceramic. At eutectic temperatures above approximately 1700C, apparent metal pick-up from the heaters was observed and radiant heating by refractory metal wires was found to be the best approach. The present emphasis is directed toward the growth of high temperature structural materials. Towards this end, a number of ingots of the Al2O3-ZrO2 eutectic containing Y2O3 as a stabilizer have been directionally solidified by the radiatively melted, floating-zone technique. (Author)

Document Details

Document Type
Technical Report
Publication Date
May 14, 1971
Accession Number
AD0723818

Entities

People

  • Charles O. Hulse
  • John A. Batt

Organizations

  • United Aircraft Corporation

Tags

DTIC Thesaurus Topics

  • Absorbers (Materials)
  • Advanced Materials
  • Biomedical And Dental Materials
  • Composite Materials
  • Directional
  • Eutectics
  • Heaters
  • High Temperature
  • Insulation
  • Materials
  • Metals
  • Microstructure
  • Radiant Heating
  • Refractory Metals
  • Temperature Gradients
  • Thermal Insulation
  • Transition Temperature

Fields of Study

  • Materials science

Readers

  • Combustion and Flow Dynamics.
  • Powder metallurgy of Titanium alloys.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene