Research into the Formation Kinetics of Polypyromellitimide by IR Absorption Spectroscopy,

Abstract

Aromatic polyimides are produced in a two-stage condensation polymerization reaction of the dianhydrides of the aromatic tetracarboxylic acid with the aromatic diamines. The first stage of the reaction is usually carried out in a strongly polar solvent at room temperature and produces a solution of polyamic acid. The second reaction stage, the imidization, consists of a chemical, or thermal, treatment of the polyamic acid that had been precipitated from the solution. In the present work, the kinetics of the thermally induced imidization of a film of polypyromellitanic acid produced from the dianhydride of the pyromellitic acid and a diaminodiphenyl ether were investigated using IR absorption spectroscopy. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1971
Accession Number
AD0726471

Entities

People

  • E. V. Kallistova
  • F. S. Florinskii
  • L. A. Laius
  • M. I. Bessonov
  • N. A. Adrova

Organizations

  • Grumman

Tags

DTIC Thesaurus Topics

  • Absorption
  • Condensation
  • Critical Temperature
  • Glass Transition Temperature
  • Kinetics
  • Polymerization
  • Spectroscopy
  • Transition Temperature

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Polymer Science and Engineering.