Research in NF Compounds
Abstract
The following phases of the program were completed and the work was assembled in the form of manuscripts: (1) Substituent Constants of Difluoraminoaklyl and Gem-bis(difluoramino)alkyl Groups, (2) Direct Fluorination of Secondary Nitronate Salts, and (3) Michael Reactions of 2-Fluoro-2,2- dinitroethanol and 2,2-Dinitropropanol with Olefinic and Acetylenic Acceptors. Nmr spectra of 2-difluoramino-2-phenylazopropane in sulfuric acid indicated initial protonation of the azo group followed by slow hydrolysis to give acetone, ammonium ion and nitrosobenzene. Spectra in fluosulfonic acid showed that a different reaction took place, possibly 1,2-shift of the phenylazo group.
Document Details
- Document Type
- Technical Report
- Publication Date
- May 01, 1969
- Accession Number
- AD0726715
Entities
People
- Kurt Baum
- Vytautas Grakauskas
Organizations
- Aerojet Rocketdyne Holdings