The Kinetics of Successive Aquation Reactions of Tetraamminepalladium(II) Ion.

Abstract

Solutions of tetraamminepalladium(II) perchlorate were made up and analyzed. Acid hydrolysis reactions of tetraamminepalladium(II) ion were studied by ultraviolet spectroscopy. First order rate constants were evaluated for each step of the reaction series at various temperatures. Activation parameters were determined. Mechanisms for the consecutive reactions are proposed, and cis and trans effects are discussed. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1971
Accession Number
AD0728702

Entities

People

  • William Jennings Deberry Jr

Organizations

  • Naval Postgraduate School

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Analog Computers
  • Analytical Chemistry
  • Chemical Compounds
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Computer Programs
  • Equations
  • Hydrolysis
  • Materials
  • Palladium
  • Perchlorates
  • Perchloric Acid
  • Spectroscopy
  • Ultraviolet Spectroscopy
  • United States

Fields of Study

  • Chemistry

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  • Organic Chemistry