Competitive Reaction Kinetics in Seeded Flames and Rocket Exhausts.

Abstract

In such non-equilibrium combustion systems as rock exhaust plumes, reactions of the types X + HY = XY + H and X + Y + M = XY + M, where X is a metal atom or free electron, Y is a free radical and M is a collision partner, compete to determine concentration ratios (XY)/(X). Competition criteria suggested by Sugden are modified, extended, and exemplified by reference to particular reactions of practical interest. The criteria help the chemist to select the minimum number of chemical reactions for computer calculations on the properties of combustion systems. Recommended rate coefficients and uncertainties are offered for several reactions of types (A) and (B). (Author)

Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1971
Accession Number
AD0729706

Entities

People

  • D. E. Jensen

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Chemical Kinetics
  • Chemical Reaction Properties
  • Chemical Reactions
  • Combustion
  • Electrons
  • Exhaust Plumes
  • Free Electrons
  • Free Radicals
  • Kinetics
  • Rocket Exhaust

Readers

  • Molecular Photonics/Laser Physics
  • Rocket Propulsion.
  • Theoretical Analysis.

Technology Areas

  • Microelectronics