Solving the Galvanic Cell Problem in Ferro-Cement

Abstract

The nature and constitution of ferro-cement is reviewed with special reference to the structure of cement paste. The microstructure of low water to- cement ratio pastes is presented in schematic illustrations to show that a thin paste layer can be used to protect steel reinforcing material from a marine environment. A galvanic cell between the plain steel reinforcing bar and the galvanized steel mesh ordinarily used in ferro-cement is identified. This galvanic cell gives off hydrogen gas at the plain steel reinforcing bar which leads to poor bonding. Possible solutions to this problem are presented and one, the use of chromium trioxide (CrO3) in the mix water, is shown to solve the problem most effectively. This leads to improved mechanical properties as well as a sounder barrier to corrosion of the reinforcement.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1971
Accession Number
AD0731719

Entities

People

  • Kenneth A Christensen
  • Robert Brady Williamson

Organizations

  • University of California, Berkeley

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Cells
  • Chemical Reactions
  • Chemistry
  • Civil Engineering
  • Construction
  • Corrosion
  • Engineering
  • Environment
  • Fabrication
  • Hydrogen
  • Material Degradation Processes
  • Materials
  • Mechanical Properties
  • Mechanical Working
  • Mechanics
  • Metals
  • Visual Inspection

Fields of Study

  • Materials science

Readers

  • Battery Technology and Engineering
  • Reinforced Composite Materials
  • Surface Coatings Technology.