Electron Spin Resonance Techniques for Nitroaromatic Cathode Depolarizer Studies.

Abstract

Radical species, which may be generated as intermediates in the electrochemical reduction of nitrosobenzene, can be identified, and their concentrations measured, with electron spin resonance techniques. The applicable experimental approach is described and evaluated for use as a kinetic tool in nitroaromatic cathode depolarizer research. 1,1-Diphenyl-2-picryl hydrazyl (DPPH) solutions were used in the calibration studies, and their behavior was critical in the selection of the optimum electrochemical solvent for studies on nitrosoaromatic radicals. (Author)

Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1971
Accession Number
AD0733340

Entities

People

  • Carol K. Pearce

Organizations

  • United States Army Communications-Electronics Command

Tags

DTIC Thesaurus Topics

  • Calibration
  • Electron Spin Resonance
  • Electrons
  • Magnetic Resonance
  • Motion
  • Nuclear Magnetic Resonance
  • Nuclear Properties
  • Nuclear Resonance
  • Physical Properties
  • Resonance
  • Spin Resonance

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Organic Chemistry
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.

Technology Areas

  • Microelectronics