A Selection Rule for the Sigma(+) Sigma(-) Transitions in Electron-Molecule Collisions.
Abstract
The differential cross section for the electron-impact excitation of the b singlet Sigma(g)(+) state from the ground state of O2 is found to decrease rapidly as the scattering angle approaches zero. This behavior is the diatomic molecule analog of 'parity-unfavored' transitions in electronatom scattering. A group theoretic argument is given which explains the observations and provides a selection rule for the Sigma(+) to Sigma(-) transitions in diatomic molecules. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Dec 01, 1971
- Accession Number
- AD0734532
Entities
People
- David C. Cartwright
- David L. Huestis
- Sandor Trajmar
- Walter Williams
Organizations
- The Aerospace Corporation