Studies of Excited Hydrogen in Relation to Advanced Propulsion.

Abstract

The report summarizes the results of research on the kinetic and energetic behavior of vibrationally excited hydrogen molecules. Excited hydrogen was generated in a microwave discharge in a low-pressure flow system. A detection method for the vibrationally excited hydrogen was developed in which gaseous hydrogen cyanide is injected into the hydrogen stream and becomes vibrationally excited through collisions with the excited hydorgen molecules; the excited HCN then emits infrared radiation at 3.0 microns. The kinetic results indicate that the most important relaxation mechanism of the vibrationally excited hydrogen is by reaction with hydrogen atoms. An automated catalytic isothermal calorimeter with direct read-out was developed for detection of the excited species. Hydrogen-atom concentrations were determined successfully. (Author)

Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1972
Accession Number
AD0739524

Entities

People

  • John M. Flournoy

Tags

DTIC Thesaurus Topics

  • Calorimeters
  • Collisions
  • Cyanides
  • Detection
  • Electromagnetic Radiation
  • Hydrogen
  • Hydrogen Cyanide
  • Infrared Radiation
  • Ionizing Radiation
  • Microwaves
  • Molecules
  • Optical Detection
  • Optical Phenomena
  • Radiation

Fields of Study

  • Chemistry

Readers

  • Chemistry (specifically Chemical Fluorescence)
  • Combustion science or combustion engineering.