A New Technique to Determine Amorphous Structure Using X-Ray Absorption Fine Structure

Abstract

A new theory for extended x-ray absorption fine structure (EXAFS) is presented which treats EXAFS as arising from the scattering of the ejected photoelectron by atoms surrounding the absorbing atom. The surrounding atoms are treated as a system of weak point scatterers which allows the scattered waves to be calculated using standard scattering theory. These scattered waves are included in the wave function of the ejected photoelectron and this is used to calculate the dipole transition matrix element from the x-ray absorption, which gives rise to oscillations in the absorption coefficient which depends on the positions of the surrounding atoms. The final result includes scattering factor, range and temperature terms and is general enough to handle any symmetry of atoms about the absorbing atom and any polarization state of the x-rays.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1972
Accession Number
AD0740216

Entities

People

  • Dale E. Sayers

Organizations

  • Boeing

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Absorption Coefficients
  • Amorphous Materials
  • Atomic Structure
  • Computer Programs
  • Convolution Integrals
  • Crystal Structure
  • Crystals
  • Diffraction
  • Electron Energy
  • Electrons
  • Equations
  • Free Electrons
  • Materials
  • Quantum Mechanics
  • Scattering
  • Standing Waves
  • Wave Functions

Fields of Study

  • Physics

Readers

  • Electromagnetic Wave Scattering and Antenna Radiation Engineering
  • Molecular Photonics/Laser Physics
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene