Kinetics of the Oxidation of Methyl Cyclohexanecarbpxylate,

Abstract

It is shown that the oxidation of methyl cyclohexanecarboxylate was done at 130C without catalyst. The activation energy of the thermal decomposition of I hydroperoxide in a medium of oxidized I depended on the presence of the oxidation products. Methyl, alpha-hydroperoxy cyclohexanecarboxylate, the primary decomposition product of tertiary I hydroperoxide, was thermally stable. Its conversion during oxidation depended on the reaction with hydroperoxide in the presence of the acids formed. (Author)

Document Details

Document Type
Technical Report
Publication Date
Feb 22, 1972
Accession Number
AD0742683

Entities

People

  • B. G. Freidin
  • Yu. Ya. Vaintraub

Organizations

  • National Air and Space Intelligence Center

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Catalysts
  • Chemical Reaction Properties
  • Chemical Reactions
  • Conversion
  • Decomposition
  • Energy
  • Heat Of Activation
  • Oxidation

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry