Thermally Stable Fluorocarbons

Abstract

The preparation of thermally stable fluoropolymers was investigated using three approaches, each based on the synthesis of a different type of fluorocarbon alkoxide monomer. Two of these alkoxides were prepared by the reaction of potassium fluoride with bis(fluorosulfonate) COMPOUNDS. One alkoxide is extremely stable, whereas the other is formed only as a transient intermediate. Neither polymerized with perfluorocyclobutene. A prototype of the third type of monomer was prepared, but it too failed to react with perfluorocyclobutene. Results indicate that the reactivity of perfluorinated alkoxides is extremely sensitive to structure.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1971
Accession Number
AD0743231

Entities

People

  • Hughie R. Frick
  • Richard W. Anderson

Tags

Communities of Interest

  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Alkali Metals
  • Alkenes
  • Boiling
  • Boiling Point
  • Chemical Reaction Properties
  • Chemical Synthesis
  • Chemistry
  • Contracts
  • Cyclobutenes
  • Ethers
  • Infrared Spectra
  • Ketones
  • Materials
  • Organic Chemistry
  • Plastic Explosives
  • Spectra
  • Spectroscopy

Fields of Study

  • Chemistry

Readers

  • Polymer Science and Technology
  • Surface Coatings Technology.