Relaxation Processes in Expanding Flows of Combustion Products

Abstract

The report presents the results of an analysis of the vibrational relaxation of a combustion gas mixture in an expanding core flow field of both a conical and contoured nozzle. The species considered are CO, H2, CO2, and H2O while the vibrational excitation is characterized through the species CO(v=1), H2(v=1), CO2(nu sub 3), CO2(nu sub 2), H2)(nu sub 3) and H2O(nu sub 2). It is found in this analysis that the vibrational modes of the diatomics effectively freeze at the nozzle exit conditions, the nu sub 2 modes of the polyatomics stay close to equilibrium with the decreasing kinetic temperature while the nu sub 3 modes freeze at intermediate values between the exit temperature and the decreasing kinetic temperature. The sensitivity of the vibrational relaxation to the assumed rate coefficients is discussed together with the influence of downstream shock structure.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1971
Accession Number
AD0746279

Entities

People

  • Edward R. Fisher
  • Frederick P. Boynton

Organizations

  • Wayne State University

Tags

Communities of Interest

  • Energy and Power Technologies
  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Air Force
  • Boundary Layer
  • Chemistry
  • Coefficients
  • Combustion
  • Combustion Products
  • Computer Programs
  • Energy
  • Energy Transfer
  • Equations
  • Equations Of Motion
  • Flow
  • Flow Fields
  • Physics Laboratories
  • Thermodynamic Properties
  • United States
  • Vibrational Relaxation

Fields of Study

  • Physics

Readers

  • Aerodynamics.
  • Fluid Dynamics.
  • Molecular Photonics/Laser Physics